Structure of Carbonyldihydridotris(triphenylphosphine)ruthenium CAS 25360-32-1

Carbonyldihydridotris(triphenylphosphine)ruthenium CAS 25360-32-1

Identification

CAS Number

25360-32-1

Name

Carbonyldihydridotris(triphenylphosphine)ruthenium

Synonyms

Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)

SMILES

[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.[RhH2]

StdInChI

InChI=1S/3C18H15P.CO.Rh.2H/c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h31-15H;;;;

StdInChIKey

WBIIBWMSHZJFCB-UHFFFAOYSA-N

Molecular Formula

C55H47OP3Rh

Molecular Weight

919.788

Properties

Appearance

Grey white to dark gray crystalline powder

Melting Point

160-162°C

Safety Data

Symbol

exclamation-mark-jpgGHS07

Signal Word

Warning

Hazard statements

H302 + H312 + H332

Precautionary Statements

P280 – P301 + P312 + P330 – P302 + P352 + P312 – P304 + P340 + P312

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

RIDADR 

NONH for all modes of transport

WGK Germany

3

Specifications and Other Information of Our Carbonyldihydridotris(triphenylphosphine)ruthenium CAS 25360-32-1

Assay

98% min

Ru

10.50% min

Storage

Stored at low temperature after vacuum packaging, can not be operated in air.

Known Application

Catalyst for converting 1,4-alkanediol to pyrrole; Catalyst for oxidation of primary alcohol to methyl ester; Catalyst for rearrangement of oxime to amide; Catalyst for C-C coupling by directional C-H activation; Catalyst for cyclopentane cyclization.

Warshel Chemical Ltd

This product is developed by our sub R&D company Warshel Chemical Ltd, and please click the link below for details. http://www.warshel.com/carbonyldihydridotris(triphenylphosphine)ruthenium-cas-25360-32-1/

Watson International Ltd

This product is sold exclusively through our sales company Watson International Ltd, and please click the link below for details. http://www.watson-int.com/carbonyldihydridotris(triphenylphosphine)ruthenium-cas-25360-32-1/