Structure of 1,1'-Bis(di-i-propylphosphino)ferrocene CAS 97239-80-0

1,1′-Bis(di-i-propylphosphino)ferrocene CAS 97239-80-0

Identification

CAS Number

97239-80-0

Name

1,1′-Bis(di-i-propylphosphino)ferrocene

Synonyms

1,1′-Bis(diisopropylphosphino)ferrocene
[ACD/IUPAC Name]
1,2,3,4,5-Cyclopentanepentayl, 1-[bis(1-methylethyl)phosphino]-, iron salt (2:1)
[ACD/Index Name]
1-(Diisopropylphosphino)-1,2,3,4,5-cyclopentanepentayl – fer (2:1)
[French]
[ACD/IUPAC Name]
1-(Diisopropylphosphino)-1,2,3,4,5-cyclopentanepentayl – iron (2:1)
[ACD/IUPAC Name]
1-(Diisopropylphosphino)-1,2,3,4,5-cyclopentanpentayl -eisen (2:1)
[German]
[ACD/IUPAC Name]
97239-80-0
[RN]
MFCD02684559
[MDL number]

SMILES

CC(C)P([C]1[CH][CH][CH][CH]1)C(C)C.CC(C)P([C]1[CH][CH][CH][CH]1)C(C)C.[Fe]

StdInChI

InChI=1S/2C11H23P.Fe/c21-9(2)12(10(3)4)11-7-5-6-8-11;/h29-11H,5-8H2,1-4H3;

StdInChIKey

XUUUHBFNNJSDAR-UHFFFAOYSA-N

Molecular Formula

C22H36FeP2

Molecular Weight

418.323

MDL Number

MFCD02684559

Properties

Appearance

Orange yellow powder

Melting Point

50-52 °C

Safety Data

RIDADR 

NONH for all modes of transport

WGK Germany

3

Specifications and Other Information of Our 1,1′-Bis(di-i-propylphosphino)ferrocene CAS 97239-80-0

Identification Methods

HNMR, HPLC

Purity

98% min

Shelf Life

2 years

Storage

Under room temperature away from light

Known Application

  1. Homogeneous catalyst ligand
    DiPPF is widely used in homogeneous catalytic reactions, especially in transition metal catalytic reactions, such as palladium-catalyzed cross-coupling reactions (such as Suzuki, Heck, Stille and Sonogashira reactions). Its diphosphine ligand structure can effectively stabilize transition metal centers such as palladium, rhodium and nickel, thereby improving the activity and selectivity of the catalyst. Due to its steric hindrance and electronic effects, DiPPF can significantly improve the yield and efficiency of catalytic reactions and has important applications in the synthesis of complex organic molecules.
  2. Drug synthesis
    In pharmaceutical chemistry, 1,1′-bis(diisopropylphosphino)ferrocene can be used as a catalyst ligand to synthesize biologically active drug molecules. Its catalytic system helps to reduce side reactions and improve the selectivity of target products, which is of great significance in the development of new drugs.
  3. Fine chemical synthesis
    DiPPF is widely used in the synthesis of fine chemicals, fragrances and agricultural chemicals, especially chemical reactions that require high selectivity and high efficiency. Due to its significant promotion of palladium-catalyzed coupling reactions, various complex aromatic and olefin compounds can be synthesized.
  4. Materials Science
    In materials science, DiPPF can be used to synthesize organic electronic materials and functional polymers, such as materials for organic light-emitting diodes (OLEDs) and organic photovoltaic cells (OPVs). Its ligand effect helps to regulate the electronic properties of metal centers, thereby improving the optoelectronic properties of materials.
  5. Academic Research
    In academic research, 1,1′-bis(diisopropylphosphino)ferrocene is widely used as a model ligand to study metal-ligand interactions, catalytic reaction mechanisms, and the development of new catalytic systems. It is used as a tool in coordination chemistry to study different metal complexes and to explore the structure-activity relationship of catalysts.

General View of Documents

This product is developed by our R&D company Warshel Chemical Ltd (https://www.warshel.com/).

This product is developed by our R&D company Watson International Ltd (https://www.watson-int.com/).